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Abstract High-eccentricity gas giant planets serve as unique laboratories for studying the thermal and chemical properties of H/He-dominated atmospheres. One of the most extreme cases is HD 80606 b—a hot Jupiter orbiting a Sun-like star with an eccentricity of 0.93—which experiences an increase in incident flux of nearly 3 orders of magnitude as the star–planet separation decreases from 0.88 au at apoastron to 0.03 au at periastron. We observed the planet’s periastron passage using JWST’s NIRSpec/G395H instrument (2.8–5.2μm) during a 21 hr window centered on the eclipse. We find that, as the planet passes through periastron, its emission spectrum transitions from a featureless blackbody to one in which CO, CH₄, and H₂O absorption features are visible. We detect CH₄during postperiapse phases at 4.1–10.7σdepending on the phase and on whether a flux offset is included to account for NRS1 detector systematics. Following periapse, H₂O and CO are also detected at 4.2–5.5σand 3.7–4.4σ, respectively. Furthermore, we rule out the presence of a strong temperature inversion near the IR photosphere based on the lack of obvious emission features throughout the observing window. General circulation models had predicted an inversion during periapse passage. Our study demonstrates the feasibility of studying hot Jupiter atmospheres using partial phase curves obtained with NIRSpec/G395H. 

Abstract JWST has ushered in an era of unprecedented ability to characterize exoplanetary atmospheres. While there are over 5000 confirmed planets, more than 4000 Transiting Exoplanet Survey Satellite (TESS) planet candidates are still unconfirmed and many of the best planets for atmospheric characterization may remain to be identified. We present a sample of TESS planets and planet candidates that we identify as “best-in-class” for transmission and emission spectroscopy with JWST. These targets are sorted into bins across equilibrium temperatureT_eqand planetary radiusR_pand are ranked by a transmission and an emission spectroscopy metric (TSM and ESM, respectively) within each bin. We perform cuts for expected signal size and stellar brightness to remove suboptimal targets for JWST. Of the 194 targets in the resulting sample, 103 are unconfirmed TESS planet candidates, also known as TESS Objects of Interest (TOIs). We perform vetting and statistical validation analyses on these 103 targets to determine which are likely planets and which are likely false positives, incorporating ground-based follow-up from the TESS Follow-up Observation Program to aid the vetting and validation process. We statistically validate 18 TOIs, marginally validate 31 TOIs to varying levels of confidence, deem 29 TOIs likely false positives, and leave the dispositions for four TOIs as inconclusive. Twenty-one of the 103 TOIs were confirmed independently over the course of our analysis. We intend for this work to serve as a community resource and motivate formal confirmation and mass measurements of each validated planet. We encourage more detailed analysis of individual targets by the community.